Zhong‐Ning Xu
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View article: Extensive halogenated organic compound reservoirs and active microbial dehalogenation in Mariana Trench sediments
Extensive halogenated organic compound reservoirs and active microbial dehalogenation in Mariana Trench sediments Open
The hadal trenches, the deepest regions of the ocean, serve as the final sinks for marine particles and "tunnels" for material exchange between the ocean and Earth's interior. Despite their extreme conditions, the trench sediments contain …
View article: The Cooperation of Pd center and Lewis Acid Sites to Achieve High Selectivity Towards Kinetic Carbonate Product for Oxidative Carbonylation Reaction
The Cooperation of Pd center and Lewis Acid Sites to Achieve High Selectivity Towards Kinetic Carbonate Product for Oxidative Carbonylation Reaction Open
Dimethyl carbonate and dimethyl oxalate are competitive products of the carbonylation reaction of methyl nitrite (MN) under Pd‐based catalysts. The chemo‐selectivity is influenced not just by the thermodynamic constraints of reaction condi…
View article: CO esterification to methyl formate: from Pd nanoparticles to single atom catalysts
CO esterification to methyl formate: from Pd nanoparticles to single atom catalysts Open
Compared to the Pd NP /α-Al 2 O 3 catalyst, the Pd 1 /(ZnMn 2 O 4 @MnO 2 ) (Pd 1 /ZMO) catalyst exhibits significantly reduced noble metal loading from 1 wt% to 0.25 wt%, while increasing the mass activity by 4 times for the CO esterificat…
View article: Frontispiece: Selectivity Control in the Direct CO Esterification over Pd@UiO‐66: The Pd Location Matters
Frontispiece: Selectivity Control in the Direct CO Esterification over Pd@UiO‐66: The Pd Location Matters Open
Heterogeneous Catalysis. In their Research Article (e202311625), Weijie Yang, Hai-Long Jiang et al. incorporate Pd nanoparticles into MOFs. The obtained catalyst exhibits high selectivity for dimethyl carbonate in the direct CO esterificat…
View article: Frontispiz: Selectivity Control in the Direct CO Esterification over Pd@UiO‐66: The Pd Location Matters
Frontispiz: Selectivity Control in the Direct CO Esterification over Pd@UiO‐66: The Pd Location Matters Open
Heterogeneous Catalysis. In their Research Article (e202311625), Weijie Yang, Hai-Long Jiang et al. incorporate Pd nanoparticles into MOFs. The obtained catalyst exhibits high selectivity for dimethyl carbonate in the direct CO esterificat…
View article: Enhanced catalytic activity for CO esterification to dimethyl oxalate via increasing Lewis basic sites in Pd/MgAl-LDO catalyst
Enhanced catalytic activity for CO esterification to dimethyl oxalate via increasing Lewis basic sites in Pd/MgAl-LDO catalyst Open
CO esterification to dimethyl oxalate (DMO) has important industrial application value. However, the influence of support on catalytic performance has not been investigated sufficiently. In this work, MgAl-LDO supports (MgAl-LDO-400 and Mg…
View article: Correcting intervertebral rotation and scoliosis simultaneously by oblique lumbar interbody fusion: a 3D analysis of EOS images
Correcting intervertebral rotation and scoliosis simultaneously by oblique lumbar interbody fusion: a 3D analysis of EOS images Open
Purpose With advancements in minimally invasive techniques, oblique lumbar interbody fusion (OLIF) has gained widespread acceptance and is now commonly performed for adult degenerative scoliosis (ADS). The objective of this research paper …
View article: Introduction of Zn<sup>2+</sup> Promotes the Catalytic Performance of Pd-based Catalyst for CO Esterification Reaction via Electron Transfer
Introduction of Zn<sup>2+</sup> Promotes the Catalytic Performance of Pd-based Catalyst for CO Esterification Reaction via Electron Transfer Open
Zn 2+ 通过电子转移提升 CO 酯化反应 Pd 基催化剂性能 刘洵 ab 江辉波 a 荆凯强 a 徐忠宁 * a 郭国聪 * a ( a 中国科学院福建物质结构研究所 结构化学国家重点实验室 福建福州 350002; b 中国科学院大学 北京 100049) 摘要 煤制乙二醇是现代煤化工中的一个重要技术路线, 其中 CO 酯化反应合成草酸二甲酯(DMO)是关键步骤之 一. 负载型 Pd 基催化剂可有效催化该反应, 但关于载体效应的研究相对较少.本研究使用二维层状材料 C…
View article: Lewis Acid in NaY Zeolite High Selectively Catalyze Methanol to Dimethoxymethane via Methyl Nitrite<sup>※</sup>
Lewis Acid in NaY Zeolite High Selectively Catalyze Methanol to Dimethoxymethane via Methyl Nitrite<sup>※</sup> Open
作为一种基础有机化学品, 在树脂、溶剂、燃料等领域具有广泛用途
View article: Porous Bismuth Nanoflowers Enriched with Lattice Dislocations for Highly Efficient Electrocatalytic Reduction of Carbon Dioxide to Formate<sup>※</sup>
Porous Bismuth Nanoflowers Enriched with Lattice Dislocations for Highly Efficient Electrocatalytic Reduction of Carbon Dioxide to Formate<sup>※</sup> Open
林姗姗 a,b 郭国聪 * ,b ( a 福州大学化学学院 福州 350116) ( b 中国科学院福建物质结构研究所结构化学国家重点实验室 福州 350002) 摘要 二氧化碳转化已成为现今世界研究的热点.本工作采用原位电化学转化的策略, 将简单溶剂热法合成的层状甲 酸氧铋纳米花(BiOCOOH NFs)还原为带有大量晶格位错的多孔铋纳米花(p-Bi NFs).研究结果表明, p-Bi NFs 电催化二 氧化碳转化为甲酸盐具有较小的过电位(436 mV).在-1.8 V(…
View article: Plasma Promotes Dry Reforming Reaction of CH4 and CO2 at Room Temperature with Highly Dispersed NiO/γ-Al2O3 Catalyst
Plasma Promotes Dry Reforming Reaction of CH4 and CO2 at Room Temperature with Highly Dispersed NiO/γ-Al2O3 Catalyst Open
Plasma is an efficient method that can activate inert molecules such as methane and carbon dioxide in a mild environment to make them reactive. In this work, we have prepared an AE-NiO/γ-Al2O3 catalyst using an ammonia-evaporation method f…
View article: New Catalysts for Coal to Ethylene Glycol
New Catalysts for Coal to Ethylene Glycol Open
Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences has achieved the industrialization of the first generation catalysts for coal to ethylene glycol for the first time in 2009. However, there are still lots…