Ji‐Jun Zou
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View article: Oxyanions stabilized low-coordinated nickel species for efficient and durable nucleophilic electrooxidation
Oxyanions stabilized low-coordinated nickel species for efficient and durable nucleophilic electrooxidation Open
Nucleophilic oxidation reactions (NORs) are key for high-value organics in electrosynthesis, but limited by slow dehydrogenation kinetics and competing oxygen evolution reactions (OER). While low-coordinated Ni species exhibit enhanced act…
View article: Fe–N–C Support‐Enhanced Pt Catalyst for High‐Performance Oxygen Reduction
Fe–N–C Support‐Enhanced Pt Catalyst for High‐Performance Oxygen Reduction Open
Platinum‐based catalysts are highly effective for the oxygen reduction reaction (ORR), but their prohibitive cost and insufficient activity impede large‐scale commercialization. Herein, we report a Pt@Fe‐NC electrocatalyst synthesized by d…
View article: Gliding arc plasma dry reforming of n-dodecane for H2 production: A mechanism study combined with experimental methods and kinetic modeling
Gliding arc plasma dry reforming of n-dodecane for H2 production: A mechanism study combined with experimental methods and kinetic modeling Open
Dry reforming technology is promising because it can simultaneously produce syngas (H2 and CO) and efficiently convert the greenhouse gas CO2. This study investigated the dry reforming (DR) of n-dodecane in a gliding arc plasma (GAP) react…
View article: Fundamentals and Perspectives on Materials for Bifunctional Electrocatalysis
Fundamentals and Perspectives on Materials for Bifunctional Electrocatalysis Open
Electrocatalysts are the core material for water electrolysis, as a promising technology for green hydrogen production coupled with renewable energy resources. Among various electrocatalyst development strategies, bifunctional electrocatal…
View article: Oxygen-doped carbon-supported palladium nanoparticles boost the tandem hydrogenation–acetalization–hydrogenolysis of phenols and diphenyl ethers to cyclohexyl ethers
Oxygen-doped carbon-supported palladium nanoparticles boost the tandem hydrogenation–acetalization–hydrogenolysis of phenols and diphenyl ethers to cyclohexyl ethers Open
The one-pot hydrotreatment of phenols to cyclohexyl ethers is crucial but difficult to achieve for fine chemical synthesis owing to the easy overhydrogenation to cyclohexanols over traditional metal-acid bifunctional catalysts. Herein, sur…
View article: Enhancing the Activity and Stability of Pt Nanoparticles Supported on Multiscale Porous Antimony Tin Oxide for Oxygen Reduction Reaction
Enhancing the Activity and Stability of Pt Nanoparticles Supported on Multiscale Porous Antimony Tin Oxide for Oxygen Reduction Reaction Open
Pt nanoparticles dispersed on carbon supports (Pt/C) are the benchmark oxygen reduction reaction (ORR) catalysts in proton exchange membrane fuel cells (PEMFCs). However, their widespread application is hindered by severe stability degrada…
View article: Comprehensive Insight into External Field‐Driven CO<sub>2</sub> Reduction to CO: Recent Progress and Future Prospects
Comprehensive Insight into External Field‐Driven CO<sub>2</sub> Reduction to CO: Recent Progress and Future Prospects Open
Currently, thermal catalysis is the predominant method for achieving the reverse water–gas shift (RWGS) reaction for the reduction of carbon dioxide (CO 2 ) to carbon monoxide (CO), which is a crucial intermediate in the synthesis of other…
View article: Cobalt disulfide promotes the selective rearrangement–hydrodeoxygenation of furan alcohols to cyclopentenones
Cobalt disulfide promotes the selective rearrangement–hydrodeoxygenation of furan alcohols to cyclopentenones Open
Developing an efficient catalyst for converting furan alcohols to cyclopentenones for fine chemical synthesis is crucial but challenging due to the easy overhydrogenation side reactions to tetrahydrofuran alcohols and cyclopentanones. This…
View article: Fabry-Perot resonance cavity for ultra-thin GaAs negative electron affinity photocathodes
Fabry-Perot resonance cavity for ultra-thin GaAs negative electron affinity photocathodes Open
Electron accelerator and photodetector require negative electron affinity photocathode (NEA-PC) with high quantum efficiency ( QE ), short response time and low mean transverse energy ( MTE ). Finding a NEA-PC that simultaneously meets all…
View article: Solar Light-Driven Efficient Degradation of Organic Pollutants Mediated by S-Scheme MoS2@TiO2-Layered Structures
Solar Light-Driven Efficient Degradation of Organic Pollutants Mediated by S-Scheme MoS2@TiO2-Layered Structures Open
This study focuses on achieving high photocatalytic activity using MoS2/TiO2 heterostructures (MOT). To this end, MoS2 and TiO2 were synthesized by employing hydrothermal synthesis techniques, and then MoS2/TiO2 heterostructures were synth…
View article: [2+2] and [2+1] cycloaddition of myrcene for synthesis of highly strained bio-fuels with high density and high impulse
[2+2] and [2+1] cycloaddition of myrcene for synthesis of highly strained bio-fuels with high density and high impulse Open
Developing bio-fuels provides a sustainable strategy to reduce the dependence on finite fossil fuels. But biomass-based fuel molecules usually lack strained structure, resulting in undesirable density and impulse for aerospace applications…
View article: Cobalt Phosphide Decorating Metallic Cobalt With a Nitrogen‐Doped Carbon Nano‐Shell Surpasses Platinum Group Metals for Oxygen Electrocatalysis Applications
Cobalt Phosphide Decorating Metallic Cobalt With a Nitrogen‐Doped Carbon Nano‐Shell Surpasses Platinum Group Metals for Oxygen Electrocatalysis Applications Open
It has been a long‐standing challenge to cultivate capable and resilient oxygen electrocatalysts with higher activity, low price, and long lifetime to replace the commonly used platinum group metals, i.e., Pt for oxygen reduction reaction …
View article: Population pharmacokinetic study in children with vascular anomalies: body weight as a key variable in predicting the initial dose and dosing frequency of sirolimus
Population pharmacokinetic study in children with vascular anomalies: body weight as a key variable in predicting the initial dose and dosing frequency of sirolimus Open
Background The main challenges faced when using sirolimus in children with vascular anomalies (VAs) still include significant pharmacokinetic (PK) variability, uncertainty in the target concentration range, as well as inconsistencies in in…
View article: Mechanism of Brønsted-acid-promoted self-photosensitized [2+2] cycloaddition for synthesis of high-performance bio-spiral fuel
Mechanism of Brønsted-acid-promoted self-photosensitized [2+2] cycloaddition for synthesis of high-performance bio-spiral fuel Open
Photoinduced [2 + 2] cycloaddition of biomass-derived cycloolefin is a promising approach to synthesize high-energy bio-fuels, however, the conversion efficiency and selectivity are still low. Herein, we provide an acid-promoted photocyclo…
View article: Mechanism and kinetics of self‐sensitized photocycloaddition of cyclohexenone and norbornene
Mechanism and kinetics of self‐sensitized photocycloaddition of cyclohexenone and norbornene Open
Solar‐driven conversion of renewable biomass resources into high‐density hydrocarbon fuels can effectively realize biomass valorization and renewable energy conversion. In this work, an efficient self‐sensitized [2 + 2] photocycloaddition …
View article: Molybdenum tungsten hydrogen oxide doped with phosphorus for enhanced oxygen/hydrogen evolution reactions
Molybdenum tungsten hydrogen oxide doped with phosphorus for enhanced oxygen/hydrogen evolution reactions Open
The development of efficient electrocatalysts for hydrogen and oxygen evolution reactions (HER and OER) is pivotal for advancing cleaner and sustainable fuel production technologies.
View article: Fe–Co heteronuclear atom pairs as catalytic sites for efficient oxygen electroreduction
Fe–Co heteronuclear atom pairs as catalytic sites for efficient oxygen electroreduction Open
Single-site Fe–N–C catalysts are the most promising Pt-group catalyst alternatives for the oxygen reduction reaction, but their application is impeded by their relatively low activity and unsatisfactory stability as well as production cost…
View article: Piezoelectric-enhanced n-TiO2/BaTiO3/p-TiO2 heterojunction for highly efficient photoelectrocatalysis
Piezoelectric-enhanced n-TiO2/BaTiO3/p-TiO2 heterojunction for highly efficient photoelectrocatalysis Open
Charge separation is critical for achieving efficient solar-to-hydrogen conversion, whereas piezoelectric-enhanced photoelectrochemical (PEC) systems can effectively modulate band bending and charge migration. Herein, we design an n-TiO2/B…