Dimethylaniline
View article: Ligand Structure Effects on the Stability of Cationic Zirconocene Dimethylaniline Complexes: Insights from Density Functional Theory
Ligand Structure Effects on the Stability of Cationic Zirconocene Dimethylaniline Complexes: Insights from Density Functional Theory Open
The formation of dimethylaniline complexes during zirconocene- and borate-mediated cationic polymerization significantly impacts catalyst performance. Using density functional theory at the M06-2X level, we investigated how ligand structur…
View article: Inclusion Ability and Selectivity Behavior of Selected Fused Tricyclic Host Systems in the Presence of the Aromatic Amines Aniline, <i>N</i>-Methylaniline and <i>N,N′</i>-Dimethylaniline
Inclusion Ability and Selectivity Behavior of Selected Fused Tricyclic Host Systems in the Presence of the Aromatic Amines Aniline, <i>N</i>-Methylaniline and <i>N,N′</i>-Dimethylaniline Open
View article: Developmental Toxicity and Cardiotoxicity of N, N-Dimethylaniline in Zebrafish Embryos
Developmental Toxicity and Cardiotoxicity of N, N-Dimethylaniline in Zebrafish Embryos Open
N, N-Dimethylaniline is an important chemical intermediate and an important metabolite of the pesticide Fenaminosulf. It is widely used in chemical production, but there is an extreme paucity of environmental risk assessments for N, N-dime…
View article: The synthesis, antimicrobial activity and theoretical calculations of 4-(4,5-diphenyl-1-(4-(phenyldiazenyl)phenyl)-1H-imidazol-2-yl)-N,N-dimethylaniline
The synthesis, antimicrobial activity and theoretical calculations of 4-(4,5-diphenyl-1-(4-(phenyldiazenyl)phenyl)-1H-imidazol-2-yl)-N,N-dimethylaniline Open
Aim. To synthesize 4-(4,5-diphenyl-1-(4-(phenyldiazenyl)phenyl)-1H-imidazol-2-yl)-N,N-dimethylaniline, as well as make theoretical calculations of its structure and study its antimicrobial properties. Materials and methods. The synthesis p…
View article: Synthesis and characterization of novel azo-chitosan polymer derivatives for the antimicrobial activity
Synthesis and characterization of novel azo-chitosan polymer derivatives for the antimicrobial activity Open
Azo-Chitosan-dimethylaniline polymer derivatives are promising polymers for biological applications. In this paper, chitosan reacted with 4-nitrosodimethylaniline to form azo-chitosan-dimethylaniline polymer (Chs-DAN) as the novel polymer …
View article: The Mn(VII)–H2O2 oxidation process: Abatement of electron-deficient N-containing organic compounds
The Mn(VII)–H2O2 oxidation process: Abatement of electron-deficient N-containing organic compounds Open
Chemical oxidants applied in water treatment are electrophiles, which preferentially attack sites with higher electron density. This typically results in less efficient oxidative abatement of organic compounds with electronwithdrawing subs…
View article: Thickness dependent CO2 adsorption of poly(ethyleneimine) thin films for direct air capture
Thickness dependent CO2 adsorption of poly(ethyleneimine) thin films for direct air capture Open
View article: Improving Microwave Absorption Of Polyaniline By Electrochemical Synthesis of Nickel Hexacyanoferrate And 2,4-Dimethylaniline Molecularly Imprinted Polymer
Improving Microwave Absorption Of Polyaniline By Electrochemical Synthesis of Nickel Hexacyanoferrate And 2,4-Dimethylaniline Molecularly Imprinted Polymer Open
View article: Visible-Light-Catalyzed Synthesis of Amino Alcohols from N,N-Dimethylaniline and Aryl Aldehyde
Visible-Light-Catalyzed Synthesis of Amino Alcohols from N,N-Dimethylaniline and Aryl Aldehyde Open
View article: Kinetics, thermodynamics, and DFT studies of phenols oxidative coupling reactions with 4-amino-N, N-dimethylaniline
Kinetics, thermodynamics, and DFT studies of phenols oxidative coupling reactions with 4-amino-N, N-dimethylaniline Open
A spectrophotometric method has been established for the reaction kinetics of phenol oxidative coupling with 4-amino-N, N-dimethylaniline in the presence of potassium dichromate as an oxidant to form C14H14N2O, known as phenol blue. Optimu…
View article: N,N-Dimethylaniline as corrosion inhibitor for zinc in sulphuric acid medium
N,N-Dimethylaniline as corrosion inhibitor for zinc in sulphuric acid medium Open
The inhibitive effect of N, N-Dimethylaniline (DMA) as corrosion inhibitor for zinc in 0.1, 0.3 and 0.5 M H2SO4 solutions has been investigated by using weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy (…
View article: Recombination of X-ray-Generated Radical Ion Pairs in Alkane Solution Assembles Optically Inaccessible Exciplexes from a Series of Perfluorinated para-Oligophenylenes with N,N-Dimethylaniline
Recombination of X-ray-Generated Radical Ion Pairs in Alkane Solution Assembles Optically Inaccessible Exciplexes from a Series of Perfluorinated para-Oligophenylenes with N,N-Dimethylaniline Open
We demonstrate that a series of perfluorinated para-oligophenylenes C6F5-(C6F4)n-C6F5 (n = 1–3) produce exciplexes with N,N-dimethylaniline (DMA) in degassed X-irradiated n-dodecane solutions. The optical characterization of the compounds …
View article: A Hydrocarbon Soluble, Molecular and “Complete” Al-Cocatalyst for High Temperature Olefin Polymerization
A Hydrocarbon Soluble, Molecular and “Complete” Al-Cocatalyst for High Temperature Olefin Polymerization Open
The dinuclear aluminum salt {[iBu2(DMA)Al]2(μ-H)}+[B(C6F5)4]− (AlHAl; DMA = N,N-dimethylaniline) is the prototype of a new class of molecular cocatalysts for catalytic olefin polymerization, its modular nature offering easy avenues for tai…
View article: Oxidative N-Dealkylation of N,N-Dimethylanilines by Non-Heme Manganese Catalysts
Oxidative N-Dealkylation of N,N-Dimethylanilines by Non-Heme Manganese Catalysts Open
Non-heme manganese(II) complexes [(IndH)MnIICl2] (1) and [(N4Py*)MnII(CH3CN)](ClO4)2 (2) with tridentate isoindoline and pentadentate polypyridyl ligands (IndH = 1,3-bis(2′-pyridylimino)isoindoline; N4Py* = N,N-bis(2-pyridylmethyl)-1,2- di…
View article: N,N-Dimethylaniline and Zno nanoparticles mediated photochemical transformation of metronidazole
N,N-Dimethylaniline and Zno nanoparticles mediated photochemical transformation of metronidazole Open
The present study evaluates the photochemical behavior of a nitroimidazole derivative drug metronidazole in presence of N,N dimethylaniline and ZnO nanoparticles. The photochemical behavior was examined in a photochemical reactor by irradi…
View article: Structural features localizing the ferroptosis inhibitor GIF-2197-r to lysosomes
Structural features localizing the ferroptosis inhibitor GIF-2197-r to lysosomes Open
Structural features of N , N -dimethylaniline derivatives as potent ferroptosis inhibitors:lysosomal localization and stabilization of ferrous ion complexation.
View article: TICT compounds by design: comparison of two naphthalimide-π-dimethylaniline conjugates of different lengths and ground state geometries
TICT compounds by design: comparison of two naphthalimide-π-dimethylaniline conjugates of different lengths and ground state geometries Open
Two new naphthalimide-π-dimethylaniline derivatives possess twisted charge transfer (TICT) excited states with reaction rates outcompeting dynamic solvation.
View article: PyDMA (C24H19N) органик нэгдлийн кристалл бүтцийн судалгаа
PyDMA (C24H19N) органик нэгдлийн кристалл бүтцийн судалгаа Open
Бид энэ ажлаар PyDMA (Pyrene dimethylaniline, C24H19N) органик нэгдэлийн кристалл болон молекул бүтцийг рентген дифракцын аргаар, STOI STADI 4 монокристаллын дифрактометр ашиглан, SHELXTL багц програмын тусламжтайгаар бүтцийн тайлал хийж а…
View article: Spin Orbit Coupling in Orthogonal Charge Transfer States: (TD-)DFT of Pyrene—Dimethylaniline
Spin Orbit Coupling in Orthogonal Charge Transfer States: (TD-)DFT of Pyrene—Dimethylaniline Open
The conformational dependence of the matrix element for spin–orbit coupling and of the electronic coupling for charge separation are determined for an electron donor–acceptor system containing a pyrene acceptor and a dimethylaniline donor.…
View article: Role of cytochrome P450 1A2 and N-acetyltransferase 2 in 2,6-dimethylaniline induced genotoxicity
Role of cytochrome P450 1A2 and N-acetyltransferase 2 in 2,6-dimethylaniline induced genotoxicity Open
The purpose of the current work was to assess a possible role of cytochrome P450 1A2 (CYP1A2) and N-acetyltransferase 2 (NAT2) in the metabolic activation of 2,6-dimethylaniline (2,6-DMA) and also clarify the function of DNA repair in affe…
View article: Forward and reverse dosimetry for aniline and 2,6-dimethylaniline in humans extrapolated from humanized-liver mouse data using simplified physiologically based pharmacokinetic models
Forward and reverse dosimetry for aniline and 2,6-dimethylaniline in humans extrapolated from humanized-liver mouse data using simplified physiologically based pharmacokinetic models Open
Although human urinary aniline and 2,6-dimethylaniline were unexpectedly detected in biomonitoring data, little is known about the daily intake doses of aniline and 2,6-dimethylaniline in the living environment or their relation to tolerab…
View article: Transformation of a N,N-Dimethylaniline N-oxide into a Tetrahydroquinoline Scaffold via a Formal Polonovski-Povarov Reaction
Transformation of a N,N-Dimethylaniline N-oxide into a Tetrahydroquinoline Scaffold via a Formal Polonovski-Povarov Reaction Open
0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0 6.5 7.0 7.5 8.0 f1 (ppm)
View article: Oxidation of the N,N–dimethylaniline by peroxynonanic acid in organic solvents
Oxidation of the N,N–dimethylaniline by peroxynonanic acid in organic solvents Open
The rate of oxidation reaction of the N,N–dimethylaniline with peroxynonanic acid in various organic solvents was studied. It has been found the effective rate constants ( k ) and the activation energy ( E akt ) of the studied process. Bet…
View article: Spin Orbit Coupling in Orthogonal Charge Transfer States: (TD-)DFT of Pyrene - Dimethylaniline
Spin Orbit Coupling in Orthogonal Charge Transfer States: (TD-)DFT of Pyrene - Dimethylaniline Open
The conformational dependence of the matrix element for spin-orbit coupling and of the electronic coupling for charge separation are determined for an electron donor-acceptor system containing a pyrene acceptor and a dimethylaniline donor.…
View article: KINETICS OF QUATERNIZATION BETWEEN N, N-DIMETHYLANILINE AND BENZYL CHLORIDE IN POLAR SOLVENTS-A REVISIT TO MENSHUTKIN REACTION
KINETICS OF QUATERNIZATION BETWEEN N, N-DIMETHYLANILINE AND BENZYL CHLORIDE IN POLAR SOLVENTS-A REVISIT TO MENSHUTKIN REACTION Open
This work reports an extension of Menshutkin reaction and involves the studies on kinetics of quaternization reaction between N,N-Dimethylaniline and benzyl chloride in acetone and in other various solvents at 300 K. The progress of the re…
View article: 4-(((4-Methoxyphenyl)amino)methyl)-N,N-dimethylaniline and 2-Methoxy-5-((phenylamino)methyl)phenol
4-(((4-Methoxyphenyl)amino)methyl)-N,N-dimethylaniline and 2-Methoxy-5-((phenylamino)methyl)phenol Open
Molecular structures of 4-(((4-methoxyphenyl)amino)methyl)-N,N-dimethylaniline and 2-methoxy-5-((phenylamino)methyl)phenol synthesized via Schiff bases reduction route are reported. The compounds consist of asymmetric units of C16H20N2O (1…
View article: Differences in Pharmacokinetics and Haematotoxicities of Aniline and Its Dimethyl Derivatives Orally Administered in Rats
Differences in Pharmacokinetics and Haematotoxicities of Aniline and Its Dimethyl Derivatives Orally Administered in Rats Open
Aniline and its dimethyl derivatives reportedly become haematotoxic after metabolic N-hydroxylation of their amino groups. The plasma concentrations of aniline and its dimethyl derivatives after single oral doses of 25 mg/kg in rats were q…
View article: Spectrophotometric determination of bromate with 2-bromo-N,N-dimethylaniline
Spectrophotometric determination of bromate with 2-bromo-N,N-dimethylaniline Open
International Association for Cancer Research included bromates in the group of carcinogenic chemicals. Therefore, it is important to determine the content of bromates in different objects. The purpose of this study is to develop a simple,…
View article: Electrochemical Amination of N,N-Dimethylaniline
Electrochemical Amination of N,N-Dimethylaniline Open
The process of indirect cathodic amination of N,N-dimethylaniline using the Ti(IV) – NH2OH system was studied in aqueous solutions of 7–16 M sulfuric acid at 40 ?C. An increase in the acid concentration was accompanied by a raise in the ef…
View article: Optoelectronic characteristics of as-deposited, annealed and I2 – Treated thin films of newly synthesized organic dye based on pyrrolo[2,3-b]pyrrole
Optoelectronic characteristics of as-deposited, annealed and I2 – Treated thin films of newly synthesized organic dye based on pyrrolo[2,3-b]pyrrole Open