Catalyst Free Silicone Sealants That Cure Underwater Article Swipe
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Robert Bui
,
Michael A. Brook
·
YOU?
·
· 2020
· Open Access
·
· DOI: https://doi.org/10.1002/adfm.202000737
· OA: W3015584800
YOU?
·
· 2020
· Open Access
·
· DOI: https://doi.org/10.1002/adfm.202000737
· OA: W3015584800
Silicone sealants and adhesives are widely used to prevent the ingress of water. However, silicones must normally be cured in air, as excess water inhibits or prevents cure from occurring. It is reported that aqueous solutions of the aliphatic aldehydes glutaraldehyde, glyoxal or, particularly, formaldehyde rapidly react without catalysts with a variety of aminopropyl‐modified silicone polymers to give silicone elastomers, even underwater. These products, whose properties are readily tailored by controlling the density of amino groups in the starting materials, may be 3D printed, or used both as adhesives and sealants in air or water.
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